180C holy smoke.
Copper is the go, surely. Look if the cycling pump fails then yes I’d believe the temp up in the vacuum header sections will get insanely hot but otherwise I’d eat my socks if all the water in the pipes + 400L water tank will get to 180C…
There are pressure reliefs all over the current electric water heater. Another one up on the header tank will deal with the roof unit. Bleed off excess pressure by copper pipe to the ground.
I have 0 experience but after some reading and discussion with a dash of common sense no human or animal should die.
Bigger Al I have Poly on the roof for our small kids pool. I throw it up there in the summer months. Works OK for the pool.